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Merck
CN

380229

Iodomethyl methyl ether

contains copper as stabilizer, 95%

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About This Item

Linear Formula:
ICH2OCH3
CAS Number:
Molecular Weight:
171.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
liquid
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InChI

1S/C2H5IO/c1-4-2-3/h2H2,1H3

SMILES string

COCI

InChI key

UUSXSNJAQDJKCG-UHFFFAOYSA-N

assay

95%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.546 (lit.)

bp

39 °C/20 mmHg (lit.)

solubility

organic solvents: soluble(lit.)

density

2.03 g/mL at 25 °C (lit.)

functional group

ether, iodo

storage temp.

2-8°C

Quality Level

General description

Iodomethyl methyl ether (Iodomethoxymethane) is a halo ether. Product contains copper as stabilizer. Rotational, centrifugal distortion constants and the nuclear electric quadrupole coupling constant tensor for iodomethyl methyl ether (CH3OCH2I) and its two deuterated species have been measured by microwave spectral studies. It readily undergoes methoxymethylation reaction with phosphorus, carbon, oxygen and nitrogen containing nucleophiles. It can be synthesized by reacting methylal (dimethoxymethane) with iodotrimethylsilane.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

71.6 °F - closed cup

flash_point_c

22 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Iodomethyl Methyl Ether
Jung ME, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether.
Fujitake M and Hayashi M.
Journal of Molecular Spectroscopy, 128(2), 444-455 (1988)
The carbon-hydrogen bond strength in dimethyl ether and some properties of iodomethyl methyl ether.
Cruickshank FR and Benson SW.
International Journal of Chemical Kinetics, 1(4), 381-390 (1969)

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