380229
碘甲基甲基醚
contains copper as stabilizer, 95%
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关于此项目
线性分子式:
ICH2OCH3
化学文摘社编号:
分子量:
171.97
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
95%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.546 (lit.)
沸点
39 °C/20 mmHg (lit.)
溶解性
organic solvents: soluble(lit.)
密度
2.03 g/mL at 25 °C (lit.)
官能团
ether
iodo
储存温度
2-8°C
SMILES字符串
COCI
InChI
1S/C2H5IO/c1-4-2-3/h2H2,1H3
InChI key
UUSXSNJAQDJKCG-UHFFFAOYSA-N
一般描述
Iodomethyl methyl ether (Iodomethoxymethane) is a halo ether. Product contains copper as stabilizer. Rotational, centrifugal distortion constants and the nuclear electric quadrupole coupling constant tensor for iodomethyl methyl ether (CH3OCH2I) and its two deuterated species have been measured by microwave spectral studies. It readily undergoes methoxymethylation reaction with phosphorus, carbon, oxygen and nitrogen containing nucleophiles. It can be synthesized by reacting methylal (dimethoxymethane) with iodotrimethylsilane.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
71.6 °F - closed cup
闪点(°C)
22 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Iodomethyl Methyl Ether
Jung ME, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
The carbon-hydrogen bond strength in dimethyl ether and some properties of iodomethyl methyl ether.
Cruickshank FR and Benson SW.
International Journal of Chemical Kinetics, 1(4), 381-390 (1969)
Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether.
Fujitake M and Hayashi M.
Journal of Molecular Spectroscopy, 128(2), 444-455 (1988)
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