380229
碘甲基甲基醚
contains copper as stabilizer, 95%
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关于此项目
线性分子式:
ICH2OCH3
化学文摘社编号:
分子量:
171.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
liquid
InChI
1S/C2H5IO/c1-4-2-3/h2H2,1H3
SMILES string
COCI
InChI key
UUSXSNJAQDJKCG-UHFFFAOYSA-N
assay
95%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.546 (lit.)
bp
39 °C/20 mmHg (lit.)
solubility
organic solvents: soluble(lit.)
density
2.03 g/mL at 25 °C (lit.)
functional group
ether, iodo
storage temp.
2-8°C
Quality Level
General description
Iodomethyl methyl ether (Iodomethoxymethane) is a halo ether. Product contains copper as stabilizer. Rotational, centrifugal distortion constants and the nuclear electric quadrupole coupling constant tensor for iodomethyl methyl ether (CH3OCH2I) and its two deuterated species have been measured by microwave spectral studies. It readily undergoes methoxymethylation reaction with phosphorus, carbon, oxygen and nitrogen containing nucleophiles. It can be synthesized by reacting methylal (dimethoxymethane) with iodotrimethylsilane.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Iodomethyl Methyl Ether
Jung ME, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether.
Fujitake M and Hayashi M.
Journal of Molecular Spectroscopy, 128(2), 444-455 (1988)
The carbon-hydrogen bond strength in dimethyl ether and some properties of iodomethyl methyl ether.
Cruickshank FR and Benson SW.
International Journal of Chemical Kinetics, 1(4), 381-390 (1969)
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