380768
Potassium diphenylphosphide solution
0.5 M in THF, liquid
Synonym(s):
Potassium diphenylphosphine, Diphenylphosphine potassium salt, KPPh2
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About This Item
Product Name
Potassium diphenylphosphide solution, 0.5 M in THF
form
liquid
Quality Segment
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
concentration
0.5 M in THF
density
0.929 g/mL at 25 °C
functional group
phosphine
SMILES string
[K]P(c1ccccc1)c2ccccc2
InChI
1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChI key
FCLYZQXPJKJTDR-UHFFFAOYSA-N
Application
- Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).
- Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).
- Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).
Signal Word
Danger
Storage Class
3 - Flammable liquids
Flash Point (°F)
-4.0 °F - closed cup
Flash Point (°C)
-20 °C - closed cup
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
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