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383767

Tri(2-furyl)phosphine

99%, solid

greener alternative

Greener Alternative

Synonym(s):

TFP, Tri-2-furanylphosphine, Tris(2-furanyl)phosphine, Tris(o-furyl)phosphine

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About This Item

Empirical Formula (Hill Notation):
C12H9O3P
CAS Number:
5518-52-5
Molecular Weight:
232.17
NACRES:
NA.22
PubChem Substance ID:
24863985
UNSPSC Code:
12352005
MDL number:
MFCD00151857
Beilstein/REAXYS Number:
1577564
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Product Name

Tri(2-furyl)phosphine, 99%

Quality Segment

assay

99%

form

solid

reaction suitability

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Cycloisomerizations, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Oxidations, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

greener alternative product characteristics

Catalysis
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Greener Alternative Product

bp

136 °C/4 mmHg (lit.)

mp

59-64 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

c1coc(c1)P(c2ccco2)c3ccco3

InChI

1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H

InChI key

DLQYXUGCCKQSRJ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This heteroaromatic phosphine ligand is used in palladium-catalyzed cross-coupling and other transition metal-catalyzed processes. Its furyl substituents provide a unique balance of ς-donor and ο-acceptor character, delivering distinctive electronic tuning that expands reactivity beyond conventional phosphine ligands, thus enhancing catalytic efficiency. Click here for more information.

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves

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