385409
4-Bromo-3-methylanisole
98%
Synonym(s):
2-Bromo-5-methoxytoluene
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About This Item
Linear Formula:
BrC6H3(CH3)OCH3
CAS Number:
Molecular Weight:
201.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
InChI
1S/C8H9BrO/c1-6-5-7(10-2)3-4-8(6)9/h3-5H,1-2H3
SMILES string
COc1ccc(Br)c(C)c1
InChI key
BLZNSXFQRKVFRP-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.561 (lit.)
bp
111-112 °C/15 mmHg (lit.)
solubility
water: soluble (Partially miscible)(lit.)
density
1.424 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
Related Categories
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Gloves
Regulatory Information
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Effect of cyclodextrins on electrophilic aromatic bromination in aqueous solution.
<BIG>Dumanski et al.</BIG>
Australian Journal of Chemistry, 56(11), 1107-1111 (2003)
The synthesis of (?)-aplysin and (?)-debromoaplysin.
<BIG>Yamada et al. </BIG>
Chemical Communications (Cambridge, England), 22, 1432-1432 (1968)
Discovery of orally active nonpeptide vitronectin receptor antagonists based on a 2-benzazepine Gly-Asp mimetic.
W H Miller et al.
Journal of medicinal chemistry, 43(1), 22-26 (2000-01-14)
Lucas R Moore et al.
Organic letters, 6(2), 225-228 (2004-01-16)
[reaction: see text] Sterically demanding, sulfonated arylphosphines TXPTS and TMAPTS have been applied to the aqueous-phase Heck and Suzuki coupling of aryl bromides. TXPTS provides good yields of Heck coupling products from aryl bromides at 80 degrees C, while both
A concise synthesis of the naphthoic acid component of neocarzinostatin chromophore featuring a new photocyclization reaction.
Myers et al.
Tetrahedron Letters, 37.5, 587-590 (1996)
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