387797
4-Bromo-N,N-bis(trimethylsilyl)aniline
97%
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About This Item
Linear Formula:
BrC6H4N[Si(CH3)3]2
CAS Number:
Molecular Weight:
316.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C12H22BrNSi2/c1-15(2,3)14(16(4,5)6)12-9-7-11(13)8-10-12/h7-10H,1-6H3
SMILES string
C[Si](C)(C)N(c1ccc(Br)cc1)[Si](C)(C)C
InChI key
YJYMZGDBOMZWSR-UHFFFAOYSA-N
assay
97%
form
liquid
bp
156-158 °C/23 mmHg (lit.)
density
1.121 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
Related Categories
Application
4-Bromo-N,N-bis(trimethylsilyl)aniline is an N-protected aryl reagent used in the synthesis of:
- Hydrophilic conjugated porphyrin dimers for one-photon and two-photon photodynamic therapy.
- Functionalized organometallic polymer, poly(ferrocenylsilane).
- Borylanilines such as 4-(dimesitylboryl)aniline and 4-(dimesitylboryl)-3,5-dimethylaniline.
- Silicon-containing oligomeric poly(imido-amides) (PIAs).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Silicon-containing oligomeric poly (imido-amides) with amino moieties. Synthesis, characterization and thermal studies.
Tagle L H, et al.
Royal Society of Chemistry Advances, 4(57), 30197-30210 (2014)
Synthesis of hydrophilic conjugated porphyrin dimers for one-photon and two-photon photodynamic therapy at NIR wavelengths.
Balaz M, et al.
Organic & Biomolecular Chemistry, 7(5), 874-888 (2009)
Revisiting Borylanilines: Unique Solid-State Structures and Insight into Photophysical Properties.
Sudhakar P, et al.
Organometallics, 32(10), 3129-3133 (2013)
Versatile and convenient routes to functionalized poly (ferrocenylsilanes).
Jakle F, et al.
Macromolecular Rapid Communications, 21(18), 1291-1296 (2000)
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