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Merck
CN

387797

4-Bromo-N,N-bis(trimethylsilyl)aniline

97%

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About This Item

Linear Formula:
BrC6H4N[Si(CH3)3]2
CAS Number:
Molecular Weight:
316.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
eCl@ss:
32150313
Assay:
97%
Form:
liquid
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Quality Segment

assay

97%

form

liquid

bp

156-158 °C/23 mmHg (lit.)

density

1.121 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

C[Si](C)(C)N(c1ccc(Br)cc1)[Si](C)(C)C

InChI

1S/C12H22BrNSi2/c1-15(2,3)14(16(4,5)6)12-9-7-11(13)8-10-12/h7-10H,1-6H3

InChI key

YJYMZGDBOMZWSR-UHFFFAOYSA-N

Application

4-Bromo-N,N-bis(trimethylsilyl)aniline is an N-protected aryl reagent used in the synthesis of:
  • Hydrophilic conjugated porphyrin dimers for one-photon and two-photon photodynamic therapy.
  • Functionalized organometallic polymer, poly(ferrocenylsilane).
  • Borylanilines such as 4-(dimesitylboryl)aniline and 4-(dimesitylboryl)-3,5-dimethylaniline.
  • Silicon-containing oligomeric poly(imido-amides) (PIAs).



Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

235.4 °F - closed cup

Flash Point (°C)

113 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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