388076
tert-Butyl peracetate solution
50 wt. % in odorless mineral spirits
Synonym(s):
tert -Butyl peracetate, tert -Butyl peroxyacetate
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About This Item
Linear Formula:
CH3CO3C(CH3)3
CAS Number:
Molecular Weight:
132.16
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
form
liquid
Quality Segment
t1/2
10 hr(101 °C, 0.2 M in benzene)
concentration
50 wt. % in odorless mineral spirits
refractive index
n20/D 1.412
density
0.828 g/mL at 25 °C
SMILES string
CC(=O)OOC(C)(C)C
InChI
1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
InChI key
SWAXTRYEYUTSAP-UHFFFAOYSA-N
Application
Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.
Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.
Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Asp. Tox. 1 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Org. Perox. C - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
Storage Class
5.2 - Organic peroxides and self-reacting hazardous materials
flash_point_f
98.6 °F - closed cup
flash_point_c
37 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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