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388076

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

Synonym(s):

tert -Butyl peracetate, tert -Butyl peroxyacetate

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About This Item

Linear Formula:
CH3CO3C(CH3)3
CAS Number:
107-71-1
Molecular Weight:
132.16
NACRES:
NA.23
PubChem Substance ID:
24864203
UNSPSC Code:
12162002
MDL number:
MFCD00048240
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form

liquid

Quality Segment

t1/2

10 hr(101 °C, 0.2 M in benzene)

concentration

50 wt. % in odorless mineral spirits

refractive index

n20/D 1.412

density

0.828 g/mL at 25 °C

SMILES string

CC(=O)OOC(C)(C)C

InChI

1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3

InChI key

SWAXTRYEYUTSAP-UHFFFAOYSA-N

Application

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.
Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Asp. Tox. 1 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Org. Perox. C - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

Flash Point (°F)

98.6 °F - closed cup

Flash Point (°C)

37 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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