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Merck
CN

38894

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
223437-11-4
Molecular Weight:
422.41
NACRES:
NA.22
PubChem Substance ID:
57649870
UNSPSC Code:
12352100
MDL number:
MFCD07784447

Key Documents

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Product Name

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, ≥98.0% (T)

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

description

electrochemical window -3.0 - +2.4 V

assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

functional group

fluoro

Quality Level

100

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Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.

General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN7533
BCCM6003
BCCJ6753
BCCK9979
BCCC1255

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Physicochemical characterization of 1-butyl-3-methylimidazolium and 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vranes, Milan, et al.
Journal of Chemical and Engineering Data, 57.4, 1072-1077 (2012)
Novel amperometric sensors for nitrite detection using electrodes modified with PEDOT prepared in ionic liquids
Gligor, Delia, et al.
Journal of Solid State Electrochemistry, 21.1, 281-290 (2017)
Aluminium Speciation in 1?Butyl?1?Methylpyrrolidinium Bis (trifluoromethylsulfonyl) amide/AlCl3 Mixtures
Rocher, Nathalie M., et al.
Chemistry?A European Journal , 15.14, 3435-3447 (2009)
Electrochemical behavior of oxygen/superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide room-temperature molten salt
Katayama, Yasushi, et al.
Journal of the Electrochemical Society, 152.8, E247-E250 (2005)
Electrochemical study of copper chloride complexes in the RTIL 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vainikka, Tuomas, et al.
Electrochimica Acta, 87, 739-748 (2013)
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Articles

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

离子液体的储能应用

离子液体，又叫室温离子液体，是在室温或接近室温下呈现液态的有机盐。

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