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Merck
CN

391778

2,2′-Biquinoline-4,4′-dicarboxylic acid dipotassium salt trihydrate

99%

Synonym(s):

2,2′-Bicinchoninic acid dipotassium salt, 4,4′-Dicarboxy-2,2′-biquinoline dipotassium salt, Dipotassium 2,2′-biquinoline-4,4′-dicarboxylate trihydrate

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About This Item

Empirical Formula (Hill Notation):
C20H10K2N2O4 · 3H2O
CAS Number:
Molecular Weight:
474.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
264-196-1
MDL number:
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Product Name

2,2′-Biquinoline-4,4′-dicarboxylic acid dipotassium salt trihydrate, 99%

InChI key

MUCQANVZZZELIW-UHFFFAOYSA-L

InChI

1S/C20H12N2O4.2K.3H2O/c23-19(24)13-9-17(21-15-7-3-1-5-11(13)15)18-10-14(20(25)26)12-6-2-4-8-16(12)22-18;;;;;/h1-10H,(H,23,24)(H,25,26);;;3*1H2/q;2*+1;;;/p-2

SMILES string

[K+].[K+].[H]O[H].[H]O[H].[H]O[H].[O-]C(=O)c1cc(nc2ccccc12)-c3cc(C([O-])=O)c4ccccc4n3

assay

99%

form

powder

mp

>300 °C (lit.)

Quality Level

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Application

2,2′-Biquinoline-4,4′-dicarboxylic acid dipotassium salt trihydrate (dipotassium salt of 2,2 -biquinoline- 4,4 -dicarboxylic acid trihydrate) may be used as ligand in the aerobic oxidation of alcohols (primary, secondary and benzylic) in the presence of palladium catalysts.

General description

2,2′-Biquinoline-4,4′-dicarboxylic acid dipotassium salt trihydrate is a hydrated dipotassium salt of 2,2-biquinoline-4,4-dicarboxylic acid.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Pd (II)-biquinoline catalyzed aerobic oxidation of alcohols in water.
Buffin BP, et al.
J. Mol. Catal. A: Chem., 225(1), 111-116 (2005)
Charged ligands for catalyst immobilisation and analysis.
Chisholm DM and McIndoe JS.
Dalton Transactions, 30, 3933-3945 (2008)

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