394483
Cyclobutyl methyl ketone
98%
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About This Item
Linear Formula:
C4H7COCH3
CAS Number:
Molecular Weight:
98.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
221-163-6
MDL number:
Assay:
98%
Form:
liquid
form
liquid
InChI key
JPJOOTWNILDNAW-UHFFFAOYSA-N
InChI
1S/C6H10O/c1-5(7)6-3-2-4-6/h6H,2-4H2,1H3
SMILES string
CC(=O)C1CCC1
assay
98%
refractive index
n20/D 1.432 (lit.)
bp
137-139 °C/754 mmHg (lit.)
density
0.902 g/mL at 25 °C (lit.)
Quality Level
General description
Cyclobutyl methyl ketone (CMK, methyl cyclobutyl ketone) is an alicyclic ketone. It has been synthesized by reacting cyclobutanecarbonyl chloride with magnesium salt of malonic ester. The mechanism of the photochemical reaction of gaseous mixtures of cyclobutyl methyl ketone diluted in argon has been studied by steady-state and pulsed (laser) photolysis. It′s infrared (3500 to 30cm-1) and Raman (3200 to 30cm-1) spectra in gaseous and solid state has been recorded. The UV spectra have been measured in alcohol and isooctane solution. Study on the vapour phase thermal and photodecomposition of methyl cyclobutyl ketone shows that the mode of decomposition is free radical in nature.
Application
Cyclobutyl methyl ketone may be used as a model compound to study the oxidation mechanism of pinonic acid by hydroxyl radicals.
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The Thermal Decomposition of Methyl Cyclobutyl Ketone1,2.
Daignault LG and Walters WD
Journal of the American Chemical Society, 80(3), 541-545 (1958)
Cyclobutyl methyl ketone as a model compound for pinonic acid to elucidate oxidation mechanisms.
Praplan AP, et al
Atmospheric Chemistry and Physics, 12(22), 10749-10758 (2012)
Azo-bis Nitriles. 1 Decomposition of Azo Compounds. A Special Case of Carbon-Carbon Hyperconjugation in a Free Radical Reaction.
Overberger CG and Lebovits A
Journal of the American Chemical Society, 76(10), 2722-2725 (1954)
Ultraviolet Absorption Spectra of Alicyclic Compounds. II. Methyl Cycloalkyl Ketones1.
Mariella RP and Raube RR
Journal of the American Chemical Society, 74(2), 518-521 (1952)
Experimental and theoretical study of aqueous cis-pinonic acid photolysis.
Lignell H, et al.
The Journal of Physical Chemistry A, 117(48), 12930-12945 (2013)
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