395056
Methylamine solution
2.0 M in THF
Synonym(s):
Monomethylamine
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About This Item
Linear Formula:
CH3NH2
CAS Number:
Molecular Weight:
31.06
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
741851
Concentration:
2.0 M in THF
Form:
liquid
Quality Level
vapor pressure
23.87 psi ( 55 °C), 7.24 psi ( 20 °C)
form
liquid
greener alternative product characteristics
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concentration
2.0 M in THF
density
0.861 g/mL at 25 °C
functional group
amine
greener alternative category
SMILES string
CN
InChI
1S/CH5N/c1-2/h2H2,1H3
InChI key
BAVYZALUXZFZLV-UHFFFAOYSA-N
General description
Methylamine (CH3NH2) is a simple aliphatic primary amine used as a chemical intermediate in organic synthesis. It is prominently used in the production of pesticides and solvents.
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Application
Methylamine can be used as a reagent in the synthesis of the following:
- Methylmorpholine from diethylene glycol.
- N-methylalkylamines from oxoamines via formation of imine, followed by hydrogenation using Ni catalyst.
- N-Methyldipropylenetriamine by reacting with acrylonitrile, followed by hydrogenation.
- N-methyl hydroxypyrrolidines from chlorohydrin in the presence of NaCNBH as a reducing agent.
- 2-(Methylamino)-6,7-dichloro-1,4-anthracenedione by reacting with 6,7-dichloro-1,4-anthracenedione.
Methylamine solution 2.0 M in THF can be used as a precursor that facilitates the synthesis of perovskite based materials. It can also be used as a deactivating agent to study the catalytic performance of acidic macroporous ion exchange resins. It can be annealed to reduce impurity in the grain boundaries, improve the stability and efficiency of the perovskite solar cells.
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Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
<-29.2 °F - closed cup
flash_point_c
< -34 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
监管及禁止进口产品
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Amines, aliphatic
Eller K, et al.
Ullmann's Encyclopedia of Industrial Chemistry (2000)
Synthesis and in vitro antitumor activity of substituted anthracene-1, 4-diones
Hua DH, et al.
Tetrahedron, 60(45), 10155-10163 (2004)
Jason A Draper et al.
Organic letters, 12(18), 4034-4037 (2010-08-24)
A convergent and stereoselective synthesis of 2,5-disubstituted 3-hydroxypyrrolidines has been developed that involves reductive annulation of β-iminochlorohydrins, which are readily available from β-ketochlorohydrins, and provides rapid access to a variety of 2,5-syn-pyrrolidines. Application of this process to the concise (three-step)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 395056-2L | 04061838119650 |
| 395056-4X100ML | 04061837672972 |
| 395056-800ML | 04061837672989 |
| 395056-100ML | 04061831982923 |