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Merck
CN

395099

Tris(4-fluorophenyl)phosphine

greener alternative

98%

Synonym(s):

Tri-(p-fluorophenyl)phosphine

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About This Item

Linear Formula:
(FC6H4)3P
CAS Number:
18437-78-0
Molecular Weight:
316.26
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
24864642
MDL number:
MFCD00013553
Beilstein/REAXYS Number:
919838

Key Documents

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Product Name

Tris(4-fluorophenyl)phosphine, 98%

InChI

1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

SMILES string

Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3

InChI key

GEPJPYNDFSOARB-UHFFFAOYSA-N

assay

98%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

79-83 °C (lit.)

functional group

phosphine

greener alternative category

Aligned,

Quality Level

200

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Related Categories

Application

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN1091
BCCK9733
BCCJ3317
BCCF5070
BCCD7606

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Gabriel A Odugbesi et al.
Journal of chromatography. A, 1604, 460466-460466 (2019-09-03)
Ionic liquids (ILs) are well-known in the field of separation science for their unique selectivity when used as stationary phases in gas chromatography (GC). While a significant amount of knowledge has been attained in correlating structural features of an IL

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