397326
Tetrakis(diethylamido)tin(IV)
Synonym(s):
Tetrakis(diethylamino)tin(IV)
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About This Item
Linear Formula:
[(C2H5)2N]4Sn
CAS Number:
Molecular Weight:
407.23
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/4C4H10N.Sn/c4*1-3-5-4-2;/h4*3-4H2,1-2H3;/q4*-1;+4
SMILES string
CCN(CC)[Sn](N(CC)CC)(N(CC)CC)N(CC)CC
InChI key
IFVSPCQTOMZHOP-UHFFFAOYSA-N
form
liquid
reaction suitability
core: tin
refractive index
n20/D 1.49 (lit.)
bp
110 °C/0.5 mmHg (lit.)
density
1.125 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
Tetrakis(diethylamido)tin(IV) can be used:
- As a precursor to synthesize mesoporous tin silicate xerogels via non-hydrolytic templated sol–gel synthesis. These xerogels are potential catalysts for aminolysis and for the Meerwein–Ponndorf–Verley reduction.
- To produce stable metal oxide thin films on the surface of carbon electrode materials.
- To fabricate an ultrathin layer of SnO2 on carbon nanotubes, which can be used as anodes for lithium-ion batteries. This ultrathin layer helps to enhance the cycling stability and rate capability of anodes.
General description
Tetrakis(diethylamido)tin(IV) is a volatile compound with four exchangeable ligands. It is widely used as a precursor to produce metal oxide thin films by the chemical vapor deposition method.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
102.2 °F - closed cup
flash_point_c
39 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Electrochemical properties of metal-oxide-coated carbon electrodes prepared by atomic layer deposition
James A Loussaert, et al.
Langmuir, 30, 13707-13715 (2014)
Growth of ultrathin SnO2 on carbon nanotubes by atomic layer deposition and their application in lithium-ion battery anodes
Shengyun Zhu, et al.
Applied Surface Science, 484, 600-609 (2019)
Mesoporous SnO2-SiO2 and Sn-silica-carbon nanocomposites by novel non-hydrolytic templated sol-gel synthesis
David Skoda, et al.
Royal Society of Chemistry Advances, 6, 68739-68747 (2016)
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