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Merck
CN

398799

Dichloro(1,10-phenanthroline)palladium(II)

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About This Item

Empirical Formula (Hill Notation):
C12H8Cl2N2Pd
CAS Number:
Molecular Weight:
357.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
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Quality Segment

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

SMILES string

Cl[Pd]Cl.c1cnc2c(c1)ccc3cccnc23

InChI

1S/C12H8N2.2ClH.Pd/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2

InChI key

YGAISFRMWCCXCG-UHFFFAOYSA-L

Application

Catalyst for:
  • Carbonylation of alkyl nitrites
  • Arylation reactions
  • Multiple acetylene insertions under Sonogashira reaction protocol
  • Cross-coupling reactions of pyridine carboxylic acid chlorides with alkylzinc reagents
  • Hydrophosphinylation of alkenes and alkynes
  • Heck reaction
  • Regioselective and stereoselective aminohalogenation reactions
  • Reaction of chloroenynes and chlorodienes with Grignard reagents for the synthesis of stereodefined enynes and dienes

  • Affects the aggregation of human prion protein PrP106-126


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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