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399396

Benzoin

Name: Benzoin
Brand: ALDRICH

purified by sublimation, ≥99.5%

Synonym(s):

α-Hydroxy-α-phenylacetophenone, α-Hydroxybenzyl phenyl ketone, 2-Hydroxy-2-phenylacetophenone

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About This Item

Linear Formula:

C₆H₅CH(OH)COC₆H₅

CAS Number:

119-53-9

Molecular Weight:

212.24

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24864811

EC Number:

204-331-3

Beilstein/REAXYS Number:

391839

MDL number:

MFCD00004496

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Properties

Quality Level

100

assay

≥99.5%

form

powder

purified by

sublimation

bp

194 °C/12 mmHg (lit.)

mp

134-138 °C (lit.)

SMILES string

OC(c1ccccc1)C(=O)c2ccccc2

InChI

1S/C14H12O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13,15H

InChI key

ISAOCJYIOMOJEB-UHFFFAOYSA-N

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

Description

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Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.

Javier Izquierdo et al.

Angewandte Chemie (International ed. in English), 51(47), 11686-11698 (2012-10-18)

N-Heterocyclic carbene (NHC) catalyzed transformations have emerged as powerful tactics for the construction of complex molecules. Since Stetter's report in 1975 of the total synthesis of cis-jasmon and dihydrojasmon by using carbene catalysis, the use of NHCs in total synthesis

Cytotoxic deoxybenzoins and diphenylethylenes from Arundina graminifolia.

Qiu-Fen Hu et al.

Journal of natural products, 76(10), 1854-1859 (2013-09-26)

Eight new C-4-alkylated deoxybenzoins (1-8), three new diphenylethylenes (9-11), and five known diphenylethylenes were isolated from Arundina graminifolia. The structures of 1-11 were elucidated by spectroscopic methods including extensive 1D and 2D NMR techniques. Compounds 9-11 are the first naturally

Structures and reactivities of O-methylated Breslow intermediates.

Biplab Maji et al.

Angewandte Chemie (International ed. in English), 51(41), 10408-10412 (2012-09-13)

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Global Trade Item Number

SKU	GTIN
399396-5G	04061833372449