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Merck
CN

404926

Vanadium(V) oxytriisopropoxide

Synonym(s):

Triisopropoxyvanadium(V) oxide, VTIP, Vanadium(V) trisisopropoxide oxide

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About This Item

Linear Formula:
OV(OCH(CH3)2)3
CAS Number:
5588-84-1
Molecular Weight:
244.20
NACRES:
NA.23
PubChem Substance ID:
24865281
UNSPSC Code:
12352103
EC Number:
226-997-4
MDL number:
MFCD00015017

Key Documents

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InChI key

DSGGJXAUQHKOGQ-UHFFFAOYSA-N

InChI

1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3

SMILES string

CC(C)O[V](=O)(OC(C)C)OC(C)C

form

liquid

composition

V, 20.3-21.4% titration (, by potassium permanganate)

reaction suitability

core: vanadium
reagent type: catalyst

refractive index

n20/D 1.479 (lit.)

bp

80-82 °C/2 mmHg (lit.)

density

1.035 g/mL at 25 °C (lit.)

Quality Level

200

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Application

Asymmetric Transfer Hydrogenation
Vanadium(V) oxytriisopropoxide is a building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis. Vanadium (V) oxytriisopropoxide (VOTP) may be used directly as a V precursor to dope TiO2 to form a high performance anode for lithium ion batteries.

General description

Vanadium(V) oxytriisopropoxide is a versatile liquid organometallic compound widely used as an effective solution and vapor deposition precursor, particularly in processes like chemical vapor deposition (CVD) and atomic layer deposition (ALD). Its high volatility and reactivity make it suitable for creating vanadium-based thin films, oxides, and coatings used in electronics, catalysis, and energy storage applications.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCX5923
1434750V
1434750
MKBK2918V
MKBJ3639V

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Improving the electrochemical performance of anatase titanium dioxide by vanadium doping as an anode material for lithium-ion batteries.
Anh LT, et al.
Journal of Power Sources, 243, 891-898 (2013)
Feilong Jiang et al.
Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)
The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)
Colm Glynn et al.
Nanoscale, 7(47), 20227-20237 (2015-11-18)
Devices composed of transparent materials, particularly those utilizing metal oxides, are of significant interest due to increased demand from industry for higher fidelity transparent thin film transistors, photovoltaics and a myriad of other optoelectronic devices and optics that require more

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