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Merck
CN

406341

Nickel(II) bromide ethylene glycol dimethyl ether complex

97%

Synonym(s):

(1,2-Dimethoxyethane)nickel dibromide, Dibromo(1,2-dimethoxyethane)nickel, Dibromo(1,2-dimethoxyethane)nickel(II)

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About This Item

Linear Formula:
NiBr2 · CH3OCH2CH2OCH3
CAS Number:
28923-39-9
Molecular Weight:
308.62
NACRES:
NA.23
PubChem Substance ID:
24865368
UNSPSC Code:
12352302
MDL number:
MFCD00013480
Assay:
97%
Form:
powder

Key Documents

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Product Name

Nickel(II) bromide ethylene glycol dimethyl ether complex, 97%

InChI

1S/C4H10O2.2BrH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

SMILES string

Br[Ni]Br.COCCOC

InChI key

VHSVJTYBTJCDFL-UHFFFAOYSA-L

assay

97%

form

powder

reaction suitability

core: nickel
reagent type: catalyst

application(s)

battery precursors
catalysts
material synthesis precursor

Quality Level

100

Related Categories

Application

Nickel(II) bromide ethylene glycol dimethyl ether complex can be used as a precursor for synthesizing various nickel(II) complexes. These complexes used as a catalysts for:      
  • The selective transformation of ethylene into higher-order products.     
  • The vinyl polymerization of norbornene.      
  • The preparation of poly(3-hexylthiophene) (P3HT) Kumada catalyst transfer polymerization. It facilitates good control over the molecular weight of the conjugating polymer.

General description

Nickel(II) bromide ethylene glycol dimethyl ether complex, also known as Ni(II) bromide ethylene glycol dimethyl ether complex. It is an organometallic coordination compound used as a precursor for the deposition of nickel-containing thin films. It is also found applications in organic synthesis as a Lewis acid catalyst.

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Flam. Sol. 1 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract,Skin

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

26.6 °F - Non-equilibrium method

flash_point_c

-3 °C - Non-equilibrium method

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT2155
SHBR6341
SHBN5971
SHBK8407
SHBJ9435

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Rapid flow-based synthesis of poly (3-hexylthiophene) using 2-methyltetrahydrofuran as a bio-derived reaction solvent
Bannock JH, et al.
European Polymer Journal, 80, 240-246 (2016)

Articles

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