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Merck
CN

409073

Trimethylolpropane ethoxylate triacrylate

average Mn ~428

Synonym(s):

Ethoxylated trimethylolpropane triacrylate, Polyethylene glycol trimethylolpropane ether triacrylate

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About This Item

Linear Formula:
[H2C=CHCO2(CH2CH2O)nCH2]3CC2H5
CAS Number:
28961-43-5
MDL number:
MFCD00074919
UNSPSC Code:
12162002
PubChem Substance ID:
24865619
NACRES:
NA.23

Key Documents

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form

liquid

Quality Level

100

mol wt

average Mn ~428

refractive index

n20/D 1.471 (lit.)

bp

157 °C (lit.)

density

1.11 g/mL at 25 °C

SMILES string

CCC(COCCOC(=O)C=C)(COCCOC(=O)C=C)COCCOC(=O)C=C

InChI

1S/C21H32O9/c1-5-18(22)28-12-9-25-15-21(8-4,16-26-10-13-29-19(23)6-2)17-27-11-14-30-20(24)7-3/h5-7H,1-3,8-17H2,4H3

InChI key

MTPIZGPBYCHTGQ-UHFFFAOYSA-N

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General description

Trimethylolpropane ethoxylate triacrylate belongs to the class of monomers known as acrylate esters. It exhibits low viscosity and high reactivity due presence of multiple acrylate functional groups which allows rapid polymerization and cross-linking. This monomer is widely used to prepare UV-curable resins for 3D printing, optical coatings for display devices, and dental composite restorative materials. It also possesses inherent hydrophobic characteristics suitable for applications where water resistance or moisture barrier properties are required.

Application

Trimethylolpropane ethoxylate triacrylate can be used:
  • As a cross-linking agent or a polymerizable monomer in the preparation of gel polymer electrolyte for Lithium-ion batteries. It enhances the thermal stability, ionic conductivity, and mechanical strength of the polymer.
  • As a monomer to prepare UV-curable resins via vat photopolymerization, for stereolithography (SLA) and digital light processing (DLP). These techniques have potential applications in the 3D printing of medical devices, soft robots, dental implants, Optical adhesives, and microfluidic devices.
  • To synthesize inverse micropatterned photonic crystal (PhC) films via photopolymerization for the detection of alcohol content in water.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H317,H319,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Sens. 1B

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ9917
MKCX4559
MKCW4356
MKCW4358
MKCT8382

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High-Performance and Highly Safe Solvate Ionic Liquid-Based Gel Polymer Electrolyte by Rapid UV-Curing for Lithium-Ion Batteries
Xinzhu Gao, et al.
ACS Applied Materials & Interfaces, 14, 43397-43406 (2022)
Fabrication Technique of Micropatterned Inverse Photonic Crystal Films
Matin Ashurov, et al.
Crystal Research and Technology, 58, 2300224-2300224 (2023)
Recent trends in advanced photoinitiators for vat photopolymerization 3D printing
Yinyin Bao
Macromolecular Rapid Communications, 43, 2200202-2200202 (2022)
Sophia Katharine Laney et al.
ACS nano, 14(9), 12091-12100 (2020-08-20)
Periodic nanotube arrays render enhanced functional properties through their interaction with light and matter, but to reach optimal performance for technologically prominent applications, such as wettability or photonics, structural fine-tuning is essential. Nonetheless, a universal and scalable method providing independent

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