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Merck
CN

412643

Geranylamine

90%

Synonym(s):

trans-3,7-Dimethyl-2,6-octadien-1-ylamine, trans-3,7-Dimethyl-2,6-octadienyl amine

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About This Item

Linear Formula:
(CH3)2C=CHCH2CH2C(CH3)=CHCH2NH2
CAS Number:
6246-48-6
Molecular Weight:
153.26
NACRES:
NA.22
PubChem Substance ID:
24865816
UNSPSC Code:
12352100
MDL number:
MFCD00192193
Assay:
90%
Form:
liquid

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InChI

1S/C10H19N/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8,11H2,1-3H3/b10-7+

SMILES string

[H]\C(CN)=C(\C)CC\C=C(\C)C

InChI key

AFMZGMJNKXOLEM-JXMROGBWSA-N

assay

90%

form

liquid

refractive index

n20/D 1.476 (lit.)

bp

105 °C/19 mmHg (lit.)

density

0.829 g/mL at 25 °C (lit.)

functional group

amine

Quality Level

100

Related Categories

General description

Geranylamine is an di-isoprene derivative.

Application

Geranylamine may be employed as starting reagent for the total synthesis of a naturally occurring guanidine alkaloid, Nitensidine D. It may be used for the synthesis of 5-alkylamino- and 2,5-bis(alkylamino)-[1,4]-benzoquinone.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
0000380668
0000380668
0000265845
0000265845
MKCG4677

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Laccase-mediated synthesis of 2-methoxy-3-methyl-5-(alkylamino)-and 3-methyl-2, 5-bis (alkylamino)-[1, 4]-benzoquinones.
Herter S, et al.
Journal of Molecular Catalysis. B, Enzymatic, 90, 91-97 (2013)
First total synthesis of a guanidine alkaloid Nitensidine D using immobilized ionic liquid, microwaves and formamidinesulfinic acid.
SHARMA ML and SINGH J.
Journal of Chemical Sciences (Bangalore), 126(6), 1869-1874 (2014)

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