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412783

Dimethyl 1,1-cyclopropanedicarboxylate

Name: Dimethyl 1,1-cyclopropanedicarboxylate
Brand: ALDRICH

99%

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About This Item

Linear Formula:

C₃H₄(CO₂CH₃)₂

CAS Number:

6914-71-2

Molecular Weight:

158.15

NACRES:

NA.22

PubChem Substance ID:

24865822

UNSPSC Code:

12352100

EC Number:

414-240-2

MDL number:

MFCD00192079

Assay:

99%

Form:

liquid

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Properties

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.441 (lit.)

bp

196-198 °C (lit.)

density

1.147 g/mL at 25 °C (lit.)

functional group

ester

SMILES string

COC(=O)C1(CC1)C(=O)OC

InChI

1S/C7H10O4/c1-10-5(8)7(3-4-7)6(9)11-2/h3-4H2,1-2H3

InChI key

PWLLZZMFFZUSOG-UHFFFAOYSA-N

Description

Application

Dimethyl 1,1-cyclopropanedicarboxylate may be used in the preparation of α-diazo-β-ketoester.

hcodes

H412

pcodes

P273 - P501

Hazard Classifications

Aquatic Chronic 3

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

203.0 °F - closed cup

flash_point_c

95 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Regulatory Information

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Asymmetric approach to the pentacyclic skeleton of Aspidosperma alkaloids via enantioselective intramolecular 1, 3-dipolar cycloaddition of carbonyl ylides catalyzed by chiral dirhodium (II) carboxylates.

Nambu H, et al.

Tetrahedron Letters, 50(26), 3675-3678 (2009)

Global Trade Item Number

SKU	GTIN
412783-50ML	04061832077000