414476
Ethyl 3,3-diethoxypropionate
90%, technical grade
Synonym(s):
Malonaldehydic acid ethyl ester diethylacetal
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About This Item
Linear Formula:
(C2H5O)2CHCH2CO2C2H5
CAS Number:
Molecular Weight:
190.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
234-223-1
Beilstein/REAXYS Number:
1772110
MDL number:
Assay:
90%
Form:
liquid
InChI key
SIALOQYKFQEKOG-UHFFFAOYSA-N
InChI
1S/C9H18O4/c1-4-11-8(10)7-9(12-5-2)13-6-3/h9H,4-7H2,1-3H3
SMILES string
CCOC(CC(=O)OCC)OCC
grade
technical grade
assay
90%
form
liquid
Quality Level
bp
92-93 °C/13 mmHg (lit.)
density
0.978 g/mL at 25 °C (lit.)
functional group
ester, ether
Related Categories
General description
Ethyl 3,3-diethoxypropionate participates in the Yb(OTf)3 catalyzed synthesis of dihydropyridines (DHPs).
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
183.2 °F - closed cup
flash_point_c
84 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Regulatory Information
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Construction of a quinoline ring via a 3-component reaction in water: crystal structure analysis and H-bonding patterns of a 2-aryl quinoline.
Reddy TR, et al.
Green Chemistry, 14(7), 1870-1872 (2012)
Ytterbium-catalyzed synthesis of dihydropyridines.
Sueki S, et al.
Tetrahedron Letters, 52(34), 4473-4477 (2011)
T Ram Reddy et al.
European journal of medicinal chemistry, 62, 395-404 (2013-02-06)
Montmorillonite K-10 mediated MCR of anilines, arylaldehydes and ethyl-3,3-diethoxypropionate in water afforded 2,6-unsubstituted dihydropyridines depending on the nature of anilines employed. A variety of dihydropyridines were prepared by using this green methodology in good yields and montmorillonite K-10 was found
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