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Merck
CN

415014

Vinyloxy-trimethylsilane

97%

Synonym(s):

(Trimethylsiloxy)ethylene, TMSO-ethene

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About This Item

Linear Formula:
(CH3)3SiOCH=CH2
CAS Number:
6213-94-1
Molecular Weight:
116.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24865970
EC Number:
228-281-7
Beilstein/REAXYS Number:
1738846
MDL number:
MFCD00054764
Assay:
97%
Form:
liquid

Key Documents

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InChI key

HFTNNOZFRQLFQB-UHFFFAOYSA-N

InChI

1S/C5H12OSi/c1-5-6-7(2,3)4/h5H,1H2,2-4H3

SMILES string

[H]\C([H])=C(\[H])O[Si](C)(C)C

assay

97%

form

liquid

refractive index

n20/D 1.389 (lit.)

bp

74 °C (lit.)

density

0.779 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

100

Related Categories

Other Notes

precipitate will not affect use

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBJ6877
SHBB3311V
93396EJ
16023CH
14624JE

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A novel synthetic pathway to vitisin B compounds.
Oliveira J, et al.
Tetrahedron Letters, 50(27), 3933-3935 (2009)
Inside the black box-Perspectives on transformations in catalysis.
Fogg DE.
Canadian Journal of Chemistry, 86(10), 931-941 (2008)
Color stability and spectroscopic properties of deoxyvitisins in aqueous solution
Sousa A, et al.
New. J. Chem., 38(2), 539-544 (2014)
Deoxyvitisins: a new set of pyrano-3-deoxyanthocyanidins.
Sousa A, et al.
Tetrahedron Letters, 54(35), 4785-4788 (2013)
Marcos N Eberlin
Journal of mass spectrometry : JMS, 41(2), 141-156 (2006-02-01)
This article discusses the application of gas-phase ion/molecule reactions for fine structural elucidation in mass spectrometry. This approach is illustrated via a representative collection of class- and functional group-selective reactions, a few of historical relevance as well as by more

Articles

Single-Electron Oxidation Transformations

Review SET mechanism in photoredox catalysis for sustainable reactions and rearrangement of oxaziridines.

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