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416126

Trimethylolpropane diallyl ether

Name: Trimethylolpropane diallyl ether
Brand: ALDRICH

90%

Synonym(s):

2,2-Bis(allyloxymethyl)-1-butanol

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About This Item

Linear Formula:

C₂H₅C(CH₂OCH₂CH=CH₂)₂CH₂OH

CAS Number:

682-09-7

Molecular Weight:

214.30

NACRES:

NA.23

PubChem Substance ID:

24866061

UNSPSC Code:

12162002

EC Number:

211-661-1

MDL number:

MFCD00035791

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Properties

Quality Level

200

assay

90%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

135 °C/13 mmHg (lit.)

density

0.955 g/mL at 25 °C (lit.)

SMILES string

CCC(CO)(COCC=C)COCC=C

InChI

1S/C12H22O3/c1-4-7-14-10-12(6-3,9-13)11-15-8-5-2/h4-5,13H,1-2,6-11H2,3H3

InChI key

BDKDHWOPFRTWPP-UHFFFAOYSA-N

Description

General description

Trimethylolpropane diallyl ether (TMPAE) is an unsaturated allyl ether that can be synthesized by Williamson esterification reaction in the presence of trimethylolpropane, sodium hydroxide, and allyl chloride as starting materials.

Application

TMPAE can be used in the synthesis of isophorone diisocyanate (IPDI) based tetracene monomers which can further be used in the formation of polymer dispersed liquid crystals. It can also be used in the synthesis of allyl ether based dendrimers that find potential usage in coatings.

Other Notes

remainder monoethers and triethers

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

244.4 °F - closed cup

flash_point_c

118 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Optimization of Synthetical Technology for Trimethylolpropane Diallyl Ether by Response Surface Method

ZHANG JT, et al.

Shanghai Kou Qiang yi Xue = Shanghai Journal of Stomatology, 2(25), 7671-7678 (2010)

Thermal and Mechanical Properties of Cross-Linked Photopolymers Based on Multifunctional Thiol- Urethane Ene Monomers

Senyurt AF, et al.

Macromolecules, 40(9), 3174-3182 (2007)

Visible light induced polymerization of maleimide-vinyl and maleimide-allyl ether based systems

Burget D, et al.

Polymer, 44(25), 7671-7678 (2003)

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Global Trade Item Number

SKU	GTIN
416126-1L	04061832089447
416126-250ML	04061832089454