B-Iodo-9-BBN solution

Name: B-Iodo-9-BBN solution
Brand: ALDRICH

1.0 M in hexanes

Synonym(s):

9-Iodo-9-borabicyclo[3.3.1]nonane solution

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About This Item

Empirical Formula (Hill Notation):

C₈H₁₄BI

CAS Number:

70145-42-5

Molecular Weight:

247.91

NACRES:

NA.22

PubChem Substance ID:

24866083

UNSPSC Code:

12352101

MDL number:

MFCD00192226

Form:

liquid

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Properties

form

liquid

Quality Level

100

concentration

1.0 M in hexanes

density

0.816 g/mL at 25 °C

SMILES string

IB1C2CCCC1CCC2

InChI

1S/C8H14BI/c10-9-7-3-1-4-8(9)6-2-5-7/h7-8H,1-6H2/t7-,8+

InChI key

YAYIUFDUYUYPJC-OCAPTIKFSA-N

Description

General description

B-Iodo-9-BBN is a boron-based organic compound that is commonly used as a reagent in organic synthesis for the iodoboration of alkynes, enolboration, the demethylation of phenol methyl ethers, and synthesis of boron-containing compounds.

Application

B-Iodo-9-BBN solution (1.0 M in hexanes) can be used as a Lewis acid in the selective synthesis of δ-keto esters via a Michael-type addition reaction to α,β-unsaturated ketones.