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419230

(Benzyloxycarbonylmethyl)triphenylphosphonium bromide

97%

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About This Item

Linear Formula:
C6H5CH2O2CCH2P(C6H5)3Br
CAS Number:
78385-36-1
Molecular Weight:
493.37
NACRES:
NA.22
PubChem Substance ID:
24866100
UNSPSC Code:
12352108
MDL number:
MFCD00191780
Assay:
97%
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assay

97%

reaction suitability

reaction type: C-C Bond Formation

mp

124 °C (dec.) (lit.)

functional group

phosphine, ester, phenyl

SMILES string

[Br-].O=C(C[P+](c1ccccc1)(c2ccccc2)c3ccccc3)OCc4ccccc4

InChI

1S/C27H24O2P.BrH/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h1-20H,21-22H2;1H/q+1;/p-1

InChI key

AVQABZVTPWROCF-UHFFFAOYSA-M

Application

Reactant for:
  • Atypical aza-Morita-Baylis-Hillman mechanism
  • Thermal decomposition
  • Double aza-Michael reaction
  • Cyclodextrin derivatives
  • Stereoselective preparation of α,β-unsaturated carbonyl compounds via stereoselective Wittig olefination with aldehydes under solventless conditions or ultrasonication
  • Synthesis of [difluoro(alkenylphenyl)methyl]phosphonic acids on non-crosslinked polystyrene as inhibitors of PTP-1B via Wittig reaction

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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