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420697

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

Name: <I>N</I>-(Methoxymethyl)-<I>N</I>-(trimethylsilylmethyl)benzylamine
Brand: ALDRICH

96%

Synonym(s):

N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine

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About This Item

Linear Formula:

C₆H₅CH₂N(CH₂OCH₃)CH₂Si(CH₃)₃

CAS Number:

93102-05-7

Molecular Weight:

237.41

NACRES:

NA.22

PubChem Substance ID:

24866346

UNSPSC Code:

12352116

MDL number:

MFCD00674005

Assay:

96%

Form:

liquid

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Properties

assay

96%

form

liquid

refractive index

n20/D 1.492 (lit.)

bp

76 °C/0.3 mmHg (lit.)

density

0.928 g/mL at 25 °C (lit.)

functional group

amine, ether, phenyl

SMILES string

COCN(Cc1ccccc1)C[Si](C)(C)C

InChI

1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3

InChI key

RPZAAFUKDPKTKP-UHFFFAOYSA-N

Description

Application

Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,β-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.

Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

150.8 °F - closed cup

flash_point_c

66 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Kotian, Pravin L.; et al.

Organic Process Research & Development, 9(2), 193-197 (2005)

Synthesis, 2646-2646 (2006)

Global Trade Item Number

SKU	GTIN
420697-100G	04061833547519
420697-5G	04061837790386
420697-25G	04061833509685