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420727

Chloro(dimethylsulfide)gold(I)

powder

Synonym(s):

(Dimethylsulfide)gold(I) chloride

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About This Item

Linear Formula:
(CH3)2SAuCl
CAS Number:
29892-37-3
Molecular Weight:
294.55
UNSPSC Code:
12161600
PubChem Substance ID:
24866348
NACRES:
NA.22
MDL number:
MFCD00192090
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Product Name

Chloro(dimethylsulfide)gold(I),

form

powder

Quality Segment

100

reaction suitability

core: gold, reagent type: catalyst

SMILES string

Cl[Au].CSC

InChI

1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1

InChI key

YQALRAGCVWJXGB-UHFFFAOYSA-M

Application

Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
  • chloro(trimesitylphosphine)gold(I)
  • gold(I) N-heterocyclic carbene (NHC) complexes
  • bis(carbene)gold(I) complex of ferrocenyl complexes
  • gold(I) acetylide complexes

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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