420727
Chloro(dimethylsulfide)gold(I)
powder
Synonym(s):
(Dimethylsulfide)gold(I) chloride
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About This Item
Linear Formula:
(CH3)2SAuCl
CAS Number:
Molecular Weight:
294.55
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Chloro(dimethylsulfide)gold(I),
SMILES string
Cl[Au].CSC
InChI
1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
InChI key
YQALRAGCVWJXGB-UHFFFAOYSA-M
form
powder
reaction suitability
core: gold
reagent type: catalyst
Quality Level
Related Categories
Application
Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
It can also be used to synthesize:
- chloro(trimesitylphosphine)gold(I)
- gold(I) N-heterocyclic carbene (NHC) complexes
- bis(carbene)gold(I) complex of ferrocenyl complexes
- gold(I) acetylide complexes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and anticancer properties of gold (I) and silver (I) N-heterocyclic carbene complexes
Siciliano T J, et al.
Journal of Organometallic Chemistry, 696(5), 1066-1071 (2011)
Liquid-crystalline (lsonitrile) gold (I) acetylide complexes.
Kaharu T, et al.
Journal of Materials Chemistry, 5(4), 687-692 (1995)
Chloro (dimethyl sulfide) gold (I)
Jones P G, et al.
Acta Crystallographica Section C, Crystal Structure Communications, 44(12), 2089-2091 (1988)
Intermolecular [2+ 2] Cycloaddition of Alkynes with Alkenes Catalyzed by Gold (I)
de Orbe M E, et al.
Organic Syntheses, 93, 115-126 (2003)
A cytotoxic bis (carbene) gold (I) complex of ferrocenyl complexes: synthesis and structural characterisation.
Horvath U E, et al.
New. J. Chem., 32(3), 533-539 (2008)
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