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422150

Triphenylsilanethiol

98%

Synonym(s):

Mercaptotriphenylsilane

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About This Item

Linear Formula:
(C6H5)3SiSH
CAS Number:
Molecular Weight:
292.47
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2941369
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Quality Segment

assay

98%

mp

101-104 °C (lit.)

functional group

silyl

SMILES string

S[Si](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H16SSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H

InChI key

MQDRKELSDPESDZ-UHFFFAOYSA-N

General description

Triphenylsilanethiol, also known as triphenylsilyl mercaptan, is an organosilicon compound that is commonly used as a reagent in organic synthesis. It can be used as a reagent for palladium-catalyzed cross-coupling reactions, such as the Stille coupling and the Sonogashira coupling reactions.

Application

Triphenylsilanethiol can be used as:      
  • A reactant to synthesis β-hydroxymercaptans or β-dihydroxysulfides by ring opening of epoxides.      
  • An additive in the selective C–H bond functionalization of widely available trialkylamine scaffolds.



Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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