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424889

Rhodium(II) heptafluorobutyrate dimer

Name: Rhodium(II) heptafluorobutyrate dimer
Brand: ALDRICH

97%

Synonym(s):

Dirhodium heptafluorobutyrate dimer, Dirhodium tetrakis(perfluorobutyrate), Tetrakis(perfluorobutyrato)dirhodium

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About This Item

Linear Formula:

[(CF₃CF₂CF₂CO₂)₂Rh]₂

CAS Number:

73755-28-9

Molecular Weight:

1057.93

NACRES:

NA.23

PubChem Substance ID:

24866595

UNSPSC Code:

12352302

MDL number:

MFCD00799582

Assay:

97%

Form:

powder

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Properties

Quality Segment

100

assay

97%

form

powder

reaction suitability

core: rhodium, reagent type: catalyst

mp

>300 °C (lit.)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)C(F)(F)C(F)(F)F.FC(F)(F)C(F)(F)C(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/4C4HF7O2.2Rh/c4*5-2(6,1(12)13)3(7,8)4(9,10)11;;/h4*(H,12,13);;/q;;;;2*+2/p-4

InChI key

BNCXPORMMOBRMR-UHFFFAOYSA-J

Description

Application

Recently used in the catalytic preparation of macrocycles and in the efficient synthesis of chiral β-substituted (E)-crotylsilanes.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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