424951
Ethyl (S)-(−)-2-(tert-butyldimethylsilyloxy)propionate
98%
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About This Item
Linear Formula:
CH3CH[OSi(CH3)2C(CH3)3]CO2C2H5
CAS Number:
Molecular Weight:
232.39
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
form
liquid
optical activity
[α]20/D −30°, c = 1.26 in chloroform
refractive index
n20/D 1.425 (lit.)
bp
187 °C (lit.)
density
0.875 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
CCOC(=O)[C@H](C)O[Si](C)(C)C(C)(C)C
InChI
1S/C11H24O3Si/c1-8-13-10(12)9(2)14-15(6,7)11(3,4)5/h9H,8H2,1-7H3/t9-/m0/s1
InChI key
KOBAXFIJEBLKRZ-VIFPVBQESA-N
Application
Precursor to the lactyl-3,4-didehydroproline didemnin B side chain. Starting material for the asymmetric synthesis of syn- and anti- functionalized1,2-diols.
Storage Class Code
10 - Combustible liquids not in Storage Class 3
WGK
WGK 3
Flash Point(F)
174.2 °F - closed cup
Flash Point(C)
79 °C - closed cup
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Mayer, S.C. et al.
The Journal of Organic Chemistry, 59, 5192-5192 (1994)
Solladie, G. Almario, A.
Tetrahedron Letters, 35, 1937-1937 (1994)
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