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Merck
CN

425184

Neodymium(III) trifluoromethanesulfonate

98%

Synonym(s):

Neodymium perfluoromethanesulfonate, Neodymium(III) triflate

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About This Item

Linear Formula:
Nd(CF3SO3)3
CAS Number:
Molecular Weight:
591.45
UNSPSC Code:
12161600
PubChem Substance ID:
MDL number:
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assay

98%

reaction suitability

core: neodymium, reagent type: catalyst

SMILES string

[Nd+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Nd/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

WYRSPTDNOIZOGA-UHFFFAOYSA-K

Application

A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.
Catalyst for:
  • Catalytic dehydration of fructose
  • Diels-Alder reactions of cyclopentadiene and alkyl acrylates
  • α-amination reactions of pyrazolones
  • Polymerization reactions of cyclosiloxanes
  • Direct polycondensation of dicarboxylic acids and diols
  • Regioselective reductive ring opening of benzylidene acetals
  • Paal-Knorr cyclocondensation
  • Nitration of benzene


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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The Journal of Organic Chemistry, 59, 3590-3590 (1994)



Global Trade Item Number

SKUGTIN
425184-5G04061832103945