425222
Ethyl 2-(bromomethyl)acrylate
98%
Synonym(s):
2-(Bromomethyl)acrylic acid ethyl ester, Ethyl α-(bromomethyl)acrylate, Ethyl 2-(bromomethyl)-2-propenoate, Ethyl 2-(bromomethyl)propenoate
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About This Item
Linear Formula:
CH2=C(CH2Br)CO2CH2CH3
CAS Number:
Molecular Weight:
193.04
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
970108
Quality Segment
assay
98%
refractive index
n
bp
38 °C/0.8 mmHg (lit.)
density
1.398 g/mL at 25 °C (lit.)
storage temp.
−20°C
SMILES string
[H]\C([H])=C(\CBr)C(=O)OCC
InChI
1S/C6H9BrO2/c1-3-9-6(8)5(2)4-7/h2-4H2,1H3
InChI key
MTCMFVTVXAOHNQ-UHFFFAOYSA-N
General description
Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.
Application
It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
177.8 °F - closed cup
Flash Point (°C)
81 °C - closed cup
PPE (personal protective equipment)
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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