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Merck
CN

425222

Ethyl 2-(bromomethyl)acrylate

98%

Synonym(s):

2-(Bromomethyl)acrylic acid ethyl ester, Ethyl α-(bromomethyl)acrylate, Ethyl 2-(bromomethyl)-2-propenoate, Ethyl 2-(bromomethyl)propenoate

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About This Item

Linear Formula:
CH2=C(CH2Br)CO2CH2CH3
CAS Number:
17435-72-2
Molecular Weight:
193.04
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24866620
MDL number:
MFCD00031518
Beilstein/REAXYS Number:
970108

Key Documents

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InChI

1S/C6H9BrO2/c1-3-9-6(8)5(2)4-7/h2-4H2,1H3

SMILES string

[H]\C([H])=C(\CBr)C(=O)OCC

InChI key

MTCMFVTVXAOHNQ-UHFFFAOYSA-N

assay

98%

Quality Level

200

bp

38 °C/0.8 mmHg (lit.)

density

1.398 g/mL at 25 °C (lit.)

storage temp.

−20°C

Related Categories

General description

Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.

Application

It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

177.8 °F - closed cup

flash_point_c

81 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
0000253848
0000253848
0000124990
0000124991
0000089978

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Ethyl 2?(Bromomethyl) acrylate.
Villieras J, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (1988)

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