429120
3-Methoxybenzyl bromide
98%
Synonym(s):
1-Bromomethyl-3-methoxybenzene
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About This Item
Linear Formula:
CH3OC6H4CH2Br
CAS Number:
Molecular Weight:
201.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
Product Name
3-Methoxybenzyl bromide, 98%
InChI
1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
SMILES string
COc1cccc(CBr)c1
InChI key
ZKSOJQDNSNJIQW-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.575 (lit.)
bp
152 °C (lit.)
density
1.436 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
Related Categories
Application
3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 6-(3-methoxyphenyl)-hexane-2,4-dione
- N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
- 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
- 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
General description
3-Methoxybenzyl bromide is a benzyl bromide derivative.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Aggarwal VK, et al.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Clayden J, et al.
Tetrahedron, 58(23), 4727-4733 (2002)
Highly diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives: a new general strategy to (R)-?-arylmethyl-?-butyrolactones.
Pohmakotr M, et al.
Tetrahedron Letters, 45(22), 4315-4318 (2004)
Yang Zhang et al.
The Journal of organic chemistry, 71(12), 4516-4520 (2006-06-06)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can generate carboxylic acids under neutral conditions at
Johan R Johansson et al.
The Journal of organic chemistry, 76(7), 2355-2359 (2011-03-11)
An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the primary alkyl halide
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