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429147

(Acetylacetonato)dicarbonyliridium(I)

Synonym(s):

Dicarbonyl(2,4-pentanedionato)iridium

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About This Item

Linear Formula:
Ir(acac)(CO2)
CAS Number:
14023-80-4
Molecular Weight:
347.35
NACRES:
NA.22
PubChem Substance ID:
24866841
UNSPSC Code:
12161600
MDL number:
MFCD00049135
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Quality Segment

100

reaction suitability

core: iridium, reagent type: catalyst

SMILES string

[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]

InChI

1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;

InChI key

DFIAYCFHPDOZLK-FGSKAQBVSA-M

Application

Catalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:
  • Oxidative addition of perfluoroalkyl iodides
  • Synthesis of iridium heterocycles
  • Scaffolding of iridium complexes
  • Metal carbonyl cluster synthesis
  • Mixed-bridged bimetallic d8 complex synthesis

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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