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Merck
CN

430609

Lanthanum(III) trifluoromethanesulfonate

greener alternative

Greener Alternative

99.999% trace metals basis

Synonym(s):

La(OTf)3, Lanthanum tris(trifluoromethanesulfonate), Tris(trifluoromethanesulfonato)lanthanum, Lanthanum(III) triflate, Trifluoromethanesulfonic acid lanthanum salt

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About This Item

Linear Formula:
(CF3SO3)3La
CAS Number:
Molecular Weight:
586.11
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
9009103
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Quality Segment

assay

99.999% trace metals basis

reaction suitability

core: lanthanum, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

[La+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.La/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

WGJJZRVGLPOKQT-UHFFFAOYSA-K

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This single-component catalyst is used for direct amidation of esters with amines under mild conditions for pharmaceutical synthesis and peptide chemistry. Its clean reactivity profile eliminates unwanted byproducts and simplifies workup, providing an efficient and atom-economical solution for amide bond formation, aligning with Green Chemistry principle "Atom Economy" and "Catalysis". Click here for more information.

Application

A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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