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Merck
CN

432504

Sodium amide

greener alternative

95%

Synonym(s):

Sodamide

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About This Item

Linear Formula:
NaNH2
CAS Number:
Molecular Weight:
39.01
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
EC Number:
231-971-0
MDL number:
Assay:
95%
Form:
solid
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Quality Level

assay

95%

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

bp

400 °C (lit.)

mp

210 °C (lit.)

greener alternative category

SMILES string

N[Na]

InChI

1S/H2N.Na/h1H2;/q-1;+1

InChI key

ODZPKZBBUMBTMG-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Sodium amide can support cleaner energy by enabling lightweight, high-density hydrogen storage and improving hydrogen-release kinetics helping lower operating temperatures and enhance overall system efficiency. Click here for more information.

Application

Reagent for synthesis of:
Allylic amines and amides
Antibacterials

Reagent for:
Aggregative activation and heterocyclic chemistry
Phenylation with diphenyliodonium chloride
Sodium amide (NH2Na) (95%) can be used for a variety of applications such as:
  • production of a hydrogen storage system
  • adsorption of CO2
  • fabrication of fuel cell



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pictograms

FlameCorrosion

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Water-react. 2



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Thermal decomposition kinetics of light-weight composite NaNH2-NaBH4 hydrogen storage materials for fuel cells
Bai Y, et al.
International Journal of Hydrogen Energy, 37(17), 12973-12979 (2012)
Christian Bukovec et al.
Organic & biomolecular chemistry, 9(8), 2743-2750 (2011-03-08)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks
M. Bakavoli, et al.,
Journal of Heterocyclic Chemistry, 48, 149-152 (2010)



Global Trade Item Number

SKUGTIN
432504-25G04061832109077
432504-100G04061832109060