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About This Item
Linear Formula:
[CF3SO3Os(NH3)5](O3SCF3)2
CAS Number:
Molecular Weight:
722.59
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
powder
InChI
1S/3CHF3O3S.5H3N.Os/c3*2-1(3,4)8(5,6)7;;;;;;/h3*(H,5,6,7);5*1H3;/q;;;;;;;;+3/p-3
SMILES string
N.N.N.N.N.[Os+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI key
HWGAHFXMBKZTPE-UHFFFAOYSA-K
form
powder
reaction suitability
reagent type: catalyst
core: osmium
mp
~276 °C (lit.)
Application
Useful for the dearomatization of anilines, and the stereoselective synthesis of cyclohexanediones by osmium(II)-promoted Michael additions to phenols. Precursor to Fischer carbyne complexes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Find documentation for the products that you have recently purchased in the Document Library.
Organometallics, 15, 245-245 (1996)
Spera, M.L. et al.
Journal of the American Chemical Society, 119, 12772-12772 (1997)
Journal of the American Chemical Society, 116, 6581-6581 (1994)
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