445134
2-Hydroxyacetophenone
98%
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About This Item
Linear Formula:
C6H5COCH2OH
CAS Number:
Molecular Weight:
136.15
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
mp
86-89 °C (lit.)
functional group
hydroxyl
ketone
phenyl
SMILES string
OCC(=O)c1ccccc1
InChI
1S/C8H8O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,9H,6H2
InChI key
ZWVHTXAYIKBMEE-UHFFFAOYSA-N
Application
2-Hydroxyacetophenone can be used as a starting material for the synthesis of:
- Enantioselective 1R-phenyl-1,2-ethanediol in the presence of a rhodium(III) catalyst by asymmetric transfer hydrogenation.
- Copper(II) complexes of 2-hydroxyacetophenone N-substituted thiosemicarbazones.
- Chromium, molybdenum, and ruthenium complexes of 2-hydroxyacetophenone Schiff bases.
- 2-Hydroxyacetophenone-aroyl hydrazone derivatives for inhibition of copper corrosion in nitric acid.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Na Li et al.
Molecules (Basel, Switzerland), 25(14) (2020-07-28)
Fluorophores with aggregation-induced emission enhancement (AIEE) characteristics applied in bioimaging have attracted more and more attention in recent years. In this work, a series of flavanone compounds with AIEE characteristics was developed and applied to fluorescence imaging of mitochondria and
Chromium, molybdenum and ruthenium complexes of 2-hydroxyacetophenone Schiff bases
Ali SA, et al.
Journal of Coordination Chemistry, 55(10), 1161-1170 (2002)
Resonance Raman intensity analysis of the excited-state proton transfer in 2-hydroxyacetophenone.
Peteanu LA and Mathies RA.
The Journal of Physical Chemistry, 96(17), 6910-6916 (1992)
A stereochemically well-defined rhodium (III) catalyst for asymmetric transfer hydrogenation of ketones
Matharu DS, et al.
Organic Letters, 7(24), 5489-5491 (2005)
Synthesis and structural characterization of mixed ligand ? 1-2-hydroxyacetophenone complexes of cobalt (III).
Mondal N, et al.
Polyhedron, 19(28), 2707-2711 (2000)
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