Skip to Content
Merck
CN

445274

Imino-tris(dimethylamino)phosphorane

97%

Synonym(s):

N,N,N′,N′,N″,N″-Hexamethylphosphorimidic triamide, Phosphazene base P1-H

Sign In to View Organizational & Contract Pricing.

Select a Size


About This Item

Linear Formula:
[(CH3)2N]3P=NH
CAS Number:
Molecular Weight:
178.22
UNSPSC Code:
12161700
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1933051
Assay:
97%
Form:
liquid
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/C6H19N4P/c1-8(2)11(7,9(3)4)10(5)6/h7H,1-6H3

SMILES string

CN(C)P(=N)(N(C)C)N(C)C

InChI key

GKTNLYAAZKKMTQ-UHFFFAOYSA-N

assay

97%

form

liquid

Quality Level

density

0.979 g/mL at 25 °C (lit.)

functional group

amine

Application

Imino-tris(dimethylamino)phosphorane is a base that can be used:
  • As a reagent in the deboronation of ortho and meta carboranes.
  • As an organocatalyst in the synthesis of cyclic organic carbonates using glycerol under solvent-free conditions.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Solvent-free organocatalytic preparation of cyclic organic carbonates under scalable continuous flow conditions
Wang Z, et al.
Reaction Chemistry & Engineering, 4(1), 17-26 (2019)
Studies of icosahedral carboranes with Imino-tris(dimethylamino)phosphorane, HNP(NMe2)3
Contemporary Boron Chemistry (2000)

Articles

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service