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Merck
CN

447145

Borane dimethyl sulfide complex solution

5.0 M in diethyl ether

Synonym(s):

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Linear Formula:
(CH3)2S · BH3
CAS Number:
13292-87-0
Molecular Weight:
75.97
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
24868320
MDL number:
MFCD00013189
Beilstein/REAXYS Number:
3663489

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InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

SMILES string

B.CSC

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

reaction suitability

reagent type: reductant

concentration

5.0 M in diethyl ether

bp

~34 °C

density

0.789 g/mL at 25 °C

functional group

thioether

storage temp.

2-8°C

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Application

Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

-31.0 °F - closed cup

flash_point_c

-35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBK0104
SHBJ7769
SHBF0672V
SHBB2426
23796JM

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Amine modified electrospun PIM-1 ultrafine fibers for an efficient removal of methyl orange from an aqueous system
Satilmis B and Uyar T
Applied Surface Science, 453, 220-229 (2018)
Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
Andrew J Saykin et al.
Alzheimer's & dementia : the journal of the Alzheimer's Association, 11(7), 792-814 (2015-07-22)
Genetic data from the Alzheimer's Disease Neuroimaging Initiative (ADNI) have been crucial in advancing the understanding of Alzheimer's disease (AD) pathophysiology. Here, we provide an update on sample collection, scientific progress and opportunities, conceptual issues, and future plans. Lymphoblastoid cell
A Burchert et al.
Leukemia, 29(6), 1331-1335 (2015-02-26)
A minority of chronic myeloid leukemia (CML) patients is capable of successfully discontinuing imatinib. Treatment modalities to increase this proportion are currently unknown. Here, we assessed the role of interferon alpha 2a (IFN) on therapy discontinuation in a previously reported
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