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Merck
CN

447145

Sigma-Aldrich

Borane dimethyl sulfide complex solution

5.0 M in diethyl ether

Synonym(s):

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Linear Formula:
(CH3)2S · BH3
CAS Number:
13292-87-0
Molecular Weight:
75.97
Beilstein:
3663489
MDL number:
MFCD00013189
UNSPSC Code:
12352112
PubChem Substance ID:
24868320
NACRES:
NA.22

Key Documents

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reaction suitability

reagent type: reductant

concentration

5.0 M in diethyl ether

bp

~34 °C

density

0.789 g/mL at 25 °C

functional group

thioether

storage temp.

2-8°C

SMILES string

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Application

Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019,EUH066

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

-31.0 °F - closed cup

Flash Point(C)

-35 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBK0104
SHBJ7769
SHBF0672V
SHBB2426
23796JM

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Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Amine modified electrospun PIM-1 ultrafine fibers for an efficient removal of methyl orange from an aqueous system
Satilmis B and Uyar T
Applied Surface Science, 453, 220-229 (2018)
Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
Pei-Chun Chen et al.
PloS one, 10(4), e0125257-e0125257 (2015-04-30)
Data on the use of oral anticoagulation (OAC) and antiplatelet therapy and the risk of bleeding and stroke amongst Asian patients with atrial fibrillation (AF) are limited. We investigated the risks of bleeding and stroke with use of oral anticoagulation
A Burchert et al.
Leukemia, 29(6), 1331-1335 (2015-02-26)
A minority of chronic myeloid leukemia (CML) patients is capable of successfully discontinuing imatinib. Treatment modalities to increase this proportion are currently unknown. Here, we assessed the role of interferon alpha 2a (IFN) on therapy discontinuation in a previously reported
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