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Merck
CN

447242

1,2-Bis(trimethoxysilyl)ethane

96%

Synonym(s):

1,2-Bis(trimethoxysilyl)ethane, 1,2-Ethylenebis(trimethoxysilane)

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About This Item

Linear Formula:
[-CH2Si(OCH3)3]2
CAS Number:
18406-41-2
Molecular Weight:
270.43
NACRES:
NA.23
PubChem Substance ID:
24868326
UNSPSC Code:
12352103
EC Number:
242-285-6
MDL number:
MFCD00053672

Key Documents

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InChI key

JCGDCINCKDQXDX-UHFFFAOYSA-N

InChI

1S/C8H22O6Si2/c1-9-15(10-2,11-3)7-8-16(12-4,13-5)14-6/h7-8H2,1-6H3

SMILES string

CO[Si](CC[Si](OC)(OC)OC)(OC)OC

assay

96%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

103-104 °C/5 mmHg (lit.)

density

1.073 g/mL at 25 °C (lit.)

General description

1,2-Bis(trimethoxysilyl)ethane (BTME) is a bridged alkoxysilane that can be used as an organosilica based precursor that forms mesoporous materials. It can be prepared by hydrolyzing the alkoxy groups with Si-OH to form Si-O-Si structure.

Application

BTME can be used to synthesize a shell based nanocomposite for potential application in drug delivery and encapsulation. It can also form magnetic hollow spheres which find usage in magnetic resonance imaging (MRI).
Functionalized mesoporous silica was synthesized from 1,2-bis(trimethoxysilyl)ethane.{27}

pictograms

Skull and crossbones
GHS06

signalword

Danger

hcodes

H330

Hazard Classifications

Acute Tox. 1 Inhalation

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCH7637
MKCG9137
MKBV8462V
MKBP3281V
MKBJ6577V

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Magnetic hollow spheres of periodic mesoporous organosilica and Fe3O4 nanocrystals: fabrication and structure control
Zhang L, et al.
Advanced Materials, 20(4), 805-809 (2008)
Multiscale templating of siloxane gels via polymerization-induced phase separation
Nakanishi K, et al.
Chemistry of Materials, 20(3), 1108-1115 (2007)
Very stable phosphiranes
Liedtke J, et al.
Angewandte Chemie (International ed. in English), 38(11), 1623-1626 (1999)
Mesoporous Ethane-Silicas Functionalized with trans-(1R,2R)-Diaminocyclohexane as Heterogeneous Chiral Catalysts
Jiang D, et al.
Chemistry of Materials, 17, 6154-6160 (2005)
Organic- inorganic hybrid hollow nanospheres with microwindows on the shell
Liu J, et al.
Chemistry of Materials, 163(11), 178-185 (2008)
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