447536
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
95%
Synonym(s):
Tetramethylethylene chlorophosphite
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About This Item
Quality Level
assay
95%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.471 (lit.)
bp
81.5-82 °C/13 mmHg (lit.)
density
1.149 g/mL at 25 °C (lit.)
SMILES string
CC1(C)OP(Cl)OC1(C)C
InChI
1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI key
WGPCXYWWBFBNSS-UHFFFAOYSA-N
Application
- As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.
- As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Related Content
Phosphine Ligand Application Guide
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 447536-5G | 04061832288628 |
| 447536-1G | 04061838119834 |