448109
2-Bromo-3-methylpyridine
95%
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About This Item
Empirical Formula (Hill Notation):
C6H6BrN
CAS Number:
Molecular Weight:
172.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
InChI
1S/C6H6BrN/c1-5-3-2-4-8-6(5)7/h2-4H,1H3
SMILES string
Cc1cccnc1Br
InChI key
PZSISEFPCYMBDL-UHFFFAOYSA-N
assay
95%
refractive index
n20/D 1.568 (lit.)
bp
218-219 °C (lit.)
density
1.544 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Synthesis of 2, 2'-Bipyridines: Versatile Building Blocks for Sexy Architectures and Functional Nanomaterials.
European Journal of Organic Chemistry, 2, 235-254 (2004)
Copper (ii) complexes of 2-halo-3-methylpyridine: synthesis, structure, and magnetic behaviour of Cu (2-X-3-CH 3 py) 2 X' 2 [X, X'= chlorine or bromine; py= pyridine].
Herringer SN, et al.
Dalton Transactions, 40(16), 4242-4252 (2011)
Lynne H Thomas et al.
Acta crystallographica. Section C, Crystal structure communications, 69(Pt 11), 1279-1288 (2013-11-07)
Controlled introduction of proton transfer into the design of a series of molecular complexes is described, delivering the systematic production of ionic molecular complexes (molecular salts). The controlled production of molecular salts has relevance as a potential strategy in the
Alan C Spivey et al.
Organic letters, 9(5), 891-894 (2007-02-10)
[reaction: see text] The scope and limitations of the conjugate addition of 2- and the first 4-pyridyl Gilman homocuprates to various alpha,beta-unsaturated Michael acceptors are delineated. The conjugate addition of the cuprate of 2-bromo-3-methylpyridine to (E)-methyl crotonate then diastereoselective enolate
Kelnner W R de França et al.
The Journal of organic chemistry, 67(6), 1838-1842 (2002-03-16)
2,2'-Bipyridine (bpy) and a series of dimethyl-2,2'-bipyridines were synthesized from 2-bromopyridine and 2-bromomethylpyridines, respectively, using an electrochemical process catalyzed by nickel complexes. The method is simple and efficient, with isolated yields between 58 and 98% according to the structure. We
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