449563
Borane diphenylphosphine complex
98%
Synonym(s):
(Diphenylphosphine)trihydroboron
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About This Item
Quality Level
assay
98%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Reductions, reagent type: reductant
bp
148-150 °C/10 mmHg (lit.)
mp
47-50 °C (lit.)
functional group
phosphine
SMILES string
B.[H]P(c1ccccc1)c2ccccc2
InChI
1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChI key
XUFGOLYVDOBYLK-UHFFFAOYSA-N
Application
- Nucleophilic addition reactions (anion)
- Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
- Deprotonation reactions
- Catalytic coupling with alkynyl bromides
- Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
- Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
- Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
signalword
Danger
hcodes
pcodes
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Water-react. 2
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 449563-5G | 04061833547663 |