449679
Barium isopropoxide
powder, 99% trace metals basis
Synonym(s):
Barium diisopropoxide, Barium isopropoxide, Diisopropoxybarium
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About This Item
Linear Formula:
Ba(OCH(CH3)2)2
CAS Number:
Molecular Weight:
255.50
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Level
assay
99% trace metals basis
form
powder, solid
reaction suitability
core: barium
mp
200 °C (dec.) (lit.)
SMILES string
CC(C)O[Ba]OC(C)C
InChI
1S/2C3H7O.Ba/c2*1-3(2)4;/h2*3H,1-2H3;/q2*-1;+2
InChI key
CPUJSIVIXCTVEI-UHFFFAOYSA-N
Application
For preparation of bimetallic Ba-Nb and Ba-Zr alkoxides. Asymmetric aldol reactions are promoted by a novel catalyst prepared from Ba(O-i-Pr)2.
It may be used as a catalyst for one pot preparation of symmetrical 1,5-diketones. Sol gel synthesis of ternary compound, Ba3 Li 2Ti8 O20 can be carried out by precursor reactants, barium isopropoxide, titanium isopropoxide and lithium acetate.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Self-heat. 2
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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One-pot synthesis of 1,5-diketones catalyzed by barium isopropoxide
Yanagisawa A, et al.
Tetrahedron, 63.35, 8581-8585 (2007)
Preparation of YBaCuO powder by sol-gel techniques using molecular precursors.
El Khokh N, et al.
Journal of Materials Science Letters, 8.7, 762-764 (1989)
Turevskaya, E.P. et al.
Polyhedron, 14, 1531-1531 (1995)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 449679-10G | 04061833355459 |
| 449679-2G | 04061833293416 |