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Merck
CN

451053

Bis(dichlorophosphino)methane

95%

Sustainability features

Synonym(s):

Methylenebis(dichlorophosphine), Methylenebis(phosphonous dichloride)

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About This Item

Linear Formula:
Cl2PCH2PCl2
CAS Number:
Molecular Weight:
217.79
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
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Quality Segment

assay

95%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

sustainability

Sustainability features

refractive index

n20/D 1.5940 (lit.)

density

1.601 g/mL at 25 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

ClP(Cl)CP(Cl)Cl

InChI

1S/CH2Cl4P2/c2-6(3)1-7(4)5/h1H2

InChI key

OEKLCAXLANZKPX-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This ligand creates transition metal catalysts with unique electronic properties for hydroformylation reactions with high regioselectivity. Its chloro substituents enable synthesis of tailored catalyst systems for specific applications. Click here for more information.


Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Skin Corr. 1B

supp_hazards

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

205.0 °F - closed cup

Flash Point (°C)

96.1 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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