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Merck
CN

452912

Sodium hydride

greener alternative

60 % dispersion in mineral oil

Synonym(s):

Sodium monohydride

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About This Item

Linear Formula:
NaH
CAS Number:
Molecular Weight:
24.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Form:
powder (moist, paste-like)
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form

powder (moist, paste-like)

Quality Level

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

60 % dispersion in mineral oil

mp

800 °C (dec.) (lit.)

greener alternative category

SMILES string

[Na]

InChI

1S/Na.H

InChI key

MPMYQQHEHYDOCL-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Sodium hydride (60% dispersion in mineral oil) (NaH) can be used for a variety of applications such as:
  • preparation of a plasticizer for the formation of a solid polymer electrolyte (SPE) for optoelectronic application
  • synthesis of heteroaryl thioethers, the common constituents in therapeutic compounds
  • preparation of sodium aluminum hydride (NaAlH4), which can be used as a hydrogen storage material(3)
  • a base and a reducing agent for the deprotonation of alcohols, phenols, amides, ketones, and different functional groups(4)
  • for potential usage in thermal energy storage(5)

Direct intercalation into C60 results in the superconducting material (NaH)4C60.


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pictograms

FlameCorrosion

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 1 - Met. Corr. 1 - Skin Corr. 1A - Water-react. 1

Regulatory Information

监管及禁止进口产品

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Enhanced ionic conductivity of semi-IPN solid polymer electrolytes based on star-shaped oligo (ethyleneoxy) cyclotriphosphazenes
He D, et al.
Macromolecules, 45(19), 7931-7938 (2012)
Elena Burlacu et al.
Nature communications, 8(1), 714-714 (2017-09-30)
While the protein composition of various yeast 60S ribosomal subunit assembly intermediates has been studied in detail, little is known about ribosomal RNA (rRNA) structural rearrangements that take place during early 60S assembly steps. Using a high-throughput RNA structure probing
S Scintilla et al.
Journal of inorganic biochemistry, 165, 159-169 (2016-11-28)
Since the discovery of cisplatin in the 1960s, other metal complexes have been investigated as potential antitumor agents to overcome the side-effects associated with the administration of the Pt-based drug. In line with our previous research, in this work we



Global Trade Item Number

SKUGTIN
452912-1KG04061832325897
452912-100G04061832325767
452912-5KG04061832326009
452912-5G04061832325996
452912-2KG04061832325958
452912-500G04061832325972