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459496

9-Borabicyclo[3.3.1]nonane solution

0.4 M in hexanes

Synonym(s):

9-BBN

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About This Item

Empirical Formula (Hill Notation):
C8H15B
CAS Number:
Molecular Weight:
122.02
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
605509
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Quality Segment

reaction suitability

reagent type: reductant

concentration

0.4 M in hexanes

bp

68-70 °C

density

0.691 g/mL at 25 °C

SMILES string

B1C2CCCC1CCC2

InChI

1S/C8H15B/c1-3-7-5-2-6-8(4-1)9-7/h7-9H,1-6H2/t7-,8+

InChI key

FEJUGLKDZJDVFY-OCAPTIKFSA-N

Application

Protecting group for alkenes†

Reactant for:
  • Linear SPPS synthesis of ubiquitin derivatives
  • Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
  • Intramolecular insertion of alkenes into palladium-nitrogen bonds
  • Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
  • Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids


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signalword

Danger

target_organs

Central nervous system, Nervous system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

flash_point_f

-7.6 °F - closed cup

flash_point_c

-22 °C - closed cup

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3 - Water-react. 1



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