459674
Nickel(II) bromide 2-methoxyethyl ether complex
Synonym(s):
Diglyme nickel dibromide
Sign Into View Organizational & Contract Pricing
All Photos(2)
About This Item
Linear Formula:
NiBr2 · O(CH2CH2OCH3)2
CAS Number:
Molecular Weight:
352.67
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
form:
powder
form
powder
Quality Level
reaction suitability
core: nickel
reagent type: catalyst
application(s)
battery precursors
catalysts
material synthesis precursor
SMILES string
Br[Ni]Br.COCCOCCOC
InChI
1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2
InChI key
RRSIMIHTHWYRRA-UHFFFAOYSA-L
Application
Nickel(II) bromide 2-methoxyethyl ether complex can be used as a catalyst to prepare:
- Hindered diarylmethanols and benzylic alcohols by the addition of aryl halides to various aldehydes in the presence of Zn as a reducing agent.
- Benzene-fused cyclic compounds via reductive dicarbofunctionalization of unactivated alkenes using less reactive benzyl chlorides.
- Benzylboron derivatives via C-C cross-coupling reaction between substituted 5-bromo-3-methoxy-2-(trimethylsilyl)phenyl triflate and bromomethylboronic acid pinacol ester.
- N-(Hetero)aryl sulfamides by N-arylation of sulfamides with aryl bromides in the presence of a photosensitizer.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service