461105
1,4-Dibromo-2,5-dimethoxybenzene
97%
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About This Item
Linear Formula:
Br2C6H2(OCH3)2
CAS Number:
Molecular Weight:
295.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C8H8Br2O2/c1-11-7-3-6(10)8(12-2)4-5(7)9/h3-4H,1-2H3
SMILES string
COc1cc(Br)c(OC)cc1Br
InChI key
CHCLRVOURKGRSW-UHFFFAOYSA-N
assay
97%
mp
144-149 °C (lit.)
General description
Crystal structure of 1,4-dibromo-2,5-dimethoxybenzene has been reported to be monoclinic and its asymmetric unit is composed of one-half of the molecule. Lithium diisopropylamide (LDA) mediated metallation of 1,4-dibromo-2,5-dimethoxybenzene has been proposed.
Application
1,4-Dibromo-2,5-dimethoxybenzene was used in the preparation of poly[(9,9-bis(6-(dibromohexyl)-2,7-fluorene))-alt-1,4-(2,5-dimethoxybenzene)], a water-soluble polyfluorene derivative.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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A study on the metalation of alkoxydibromobenzenes.
Da M, et al.
Tetrahedron Letters, 46(24), 4175-4178 (2005)
1, 4-Dibromo-2, 5-dimethoxybenzene.
Luo ZH, et al.
Acta Crystallographica Section E, Structure Reports Online, 66(7), o1806-o1806 (2010)
Novel cationic water-soluble polyfluorene derivatives with ion-transporting side groups for efficient electron injection in PLEDs.
Oh S-H, et al.
Organic Electronics, 8(6), 773-783 (2007)
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